Crystallization induction time

Author: rsxi

August undefined, 2024

WebAug 28, 2013 · An approximation of the crystallization rate can be made by the overall crystallization rate , where (half the crystallization time) is the time at which approaches the value of 50%. This parameter is proportional to both the primary nucleation rate and the crystal/spherulite growth [].The induction time , that is, the time at which starts to … WebApr 8, 2024 · In addition, PASP-Pro exhibited a promising anti-scaling property by inhibiting the crystallization of CaCO 3; the induction period and the nucleation period of the CaCO 3 crystallization process were prolonged nearly four times. It was found from XRD patterns that vaterite, an unstable crystalline phase, gradually emerged with the addition of ...

Crystallization Propensity of Amorphous Pharmaceuticals: …

WebMay 3, 2013 · Smejkal et al. 6 found that the induction time for crystallization of lysozyme in a stirred crystallizer was substantially shorter compared to an experiment in a nonagitated microbatch. WebApr 3, 2024 · Its crystallization induction time (λ) was long (~123 min), this being followed by a rapid crystallization rate (μ ~ 1.7%/min) before reaching an SFC plateau of 21% (Table 4). The sigmoidal curves indicated that no TAG crystallized until a sufficient number of stable nuclei were formed, followed by a period of rapid crystallization initiated ... rayen stadium youngstown ohio

Investigation of Metastable Zones and Induction Times in Glycine ...

WebApr 29, 2024 · The time–temperature superposition of PEEK 450G; the frequency-scale shift factor (a T) and modulus-scale shift factor (b T); time–temperature protocol to monitor the isothermal crystallization induction time; an illustration to define crystallization induction time; the rheological induction times obtained at T c = 322. 325, and 328 °C ... WebA relation between induction time and metastable zone width in cooling crystallization has been developed based on the correlation between temperature and supersaturation with … WebNov 24, 2024 · The observed induction time for seeded gypsum crystallization was investigated with respect to gypsum particle seed size and mass loading. The induction time was significantly shortened in the presence of gypsum seeds (27 µm - 85 µm) relative to unseeded solutions. The induction time correlated with the initial total seeds surface … ray entwistle

Induction Period for Crystallization - Wiley Online Library

WebSep 17, 2024 · With the extension of crystallization time, the relative crystallinity of YSG and YSV molecular sieves increased rapidly in a short time. After a period of crystallization, the crystallization rate slowed down, and declined after reaching their respective peaks. ... Obtained data, including the nucleation induction period, apparent … WebIt can be measured experimentally to describe the time required for the formation of an observable change in the crystallization system from the starting point of supersaturation. Figure 5 shows the induction time measurement of AM in WSC solution. The concentration of AM in the water rapidly decreased for one minute due to the crystal nuclei ... simple syrup pharmacyWebJan 27, 2015 · The induction time distribution is explained by the stochastic nature of nucleation if the number of nuclei formed is approaching 1 per vial. Accurate … simple syrup ratio for lemonade

"" - Crystallization induction time

Crystallization induction time

WebAfter a temperaturedependent induction time, during stage 2 the Mg-ACC partially dehydrates and orders prior to its rapid (<5 min) crystallization to non-stoichiometric protodolomite. This occurs via the dissolution of Mg-ACC, followed by the secondary nucleation of proto-dolomite from solution. The proto-dolomite crystallization... WebThe induction time distribution is explained by the stochastic nature of nucleation if the number of nuclei formed is approaching 1 per vial. Accurate heterogeneous crystal …

Did you know?

WebJan 25, 2024 · In other words, a PP ball reduced the induction time of form II nucleation from over 800 s to 562 ± 103 s. These results demonstrate that the presence of a plastic ball in aqueous acetaminophen solution undergoing ultrasonic irradiation effectively increases the probability and reduces the induction time of form II crystallization. WebJul 24, 2024 · This chapter gives an overview of different aspects of the induction period for crystallization carried out at predefined supersaturation created in the system at the …

WebAfter a temperature-dependent induction time, during stage 2 the Mg-ACC partially dehydrates and orders prior to its rapid (<5 min) crystallization to non-stoichiometric proto-dolomite. This occurs via the dissolution of Mg-ACC, followed by the secondary nucleation of proto-dolomite from solution. WebThe Avrami equation cannot account for a period where no crystallization occurs; therefore, induction time, t 0, denotes the initial time at which crystallization begins. An induction period in the early stage of crystallization is required for creation of nuclei and is estimated by calculating the first derivative d X / d t , because it should ...

WebWhile billion-plate crystallization arrays are probably infeasible, such an induction probability between competing polymorphs would be present each time a nucleation event occurs. For a nucleation rate of 1 nucleus … WebJan 24, 2024 · By determining the induction time, the nucleation kinetics can be calculated and used to find the thermodynamic and kinetic parameters (such as interfacial energy, critical nucleation free energy, pre-exponential factor, and critical radius and number of molecules in the nucleus) required for efficient crystallization design which will be ...

WebFeb 4, 2024 · Crystallization is a collection of the subprocesses of crystal primary nucleation, crystal growth, secondary nucleation and agglomeration, which are all governed by the prevailing supersaturation as well as other parameters. The rates of these …

WebBoth the true induction time and the crystallization rate curves were found to be similarly unsymmetrical as a function of temperature. Also, the temperature at the minimum … rayen street condos newWebIn this work, new Ge-containing Fe-based nanocrystalline alloys with the composition of Fe80.2Si3B12-xP2Nb2Cu0.8Gex (x = 0, 1, 2 at.%) were developed, and the effects of Ge content on the magnetic and crystallization processes of the alloys were investigated. The addition of Ge extends the annealing window of the present Fe-based alloys, which … rayen whiteWebAn induction period in chemical kinetics is an initial slow stage of a chemical reaction; after the induction period, the reaction accelerates. Ignoring induction periods can lead to … rayen washing machine coverWebOne study was found which observed agitated solutions at similar supersaturations and temperatures, and it can be seen that for antisolvent crystallization, at a supersaturation … ray envelopeWebThe control of crystal morphology is of foremost importance in pharmaceutical industries for drug development. The crystal features and surface properties are the key factors influencing the stability, bioavailability and dissolution properties of an active pharmaceutical ingredient (API). Knowing and being able to modify the crystal habit ... simple syrup recipe for canning peachesWebApr 11, 2024 · In absence of Mel, the induction time was approximately 12.6 times higher than at the highest level of Mel studied, suggesting that Mel acts as a promoter for UA … raye number 1WebThe crystallization of gypsum was carried out under simulated conditions of phosphoric acid production by the dihydrate process. Calcium hydrogen phosphate and sulfuric acid were mixed with dilute phosphoric acid at 80 °C, and the turbidity of the reaction mixture was measured at different time periods to calculate the induction time of gypsum ... simple syrup recipe coffee